CO2 adsorption performance of novel polyaramid-based hyper-crosslinked polymers synthesized by the Friedel-Crafts
Yazarlar (5)
Doç. Dr. Kutalmış GÖKKUŞ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Mursel Arici Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Nesrin ŞENER Kastamonu Üniversitesi, Türkiye
Doç. Dr. Cansel Tuncer Eskişehir Osmangazi Üniversitesi, Türkiye
S. Alper Akalin
Dokuz Eylül Üniversitesi, Türkiye
Dokuz Eylül Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Polymer (Q2) | ||
| Dergi ISSN | 0032-3861 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2025 |
| Cilt / Sayı / Sayfa | 324 / 1 / 128254–0 | DOI | 10.1016/j.polymer.2025.128254 |
| Makale Linki | https://doi.org/10.1016/j.polymer.2025.128254 | ||
| UAK Araştırma Alanları |
Hava Kirliliği ve Kontrolü
Temiz Üretim Teknolojileri
Su Kirliliği ve Kontrolü
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| Özet |
| In this study, new hyper-crosslinked polymers (HCPs) were synthesized by crosslinking polyaramids via the Friedel-Crafts (FC) method for the first time. Polyaramids were synthesized using p-phenylenediamine (PDA), 4-aminophenyl ether (APE), and 4-aminophenyl sulfone (APS) and crosslinked with 1,4-bis(chloromethyl)benzene (BCMB) to form HCPs. The synthesized HCPs were characterized using FT-IR, BET, SEM, and TGA. The surface areas of HCPs ranged from 442 to 582 m2 g−1, with pore volumes between 0.50 and 0.61 cm3 g−1. CO2 adsorption experiments demonstrated that HCPs exhibited significant adsorption capacities, with values of 2.25, 2.56, and 2.29 mmol g−1 for HCP-TPC1, HCP-TPC2, and HCP-TPC3, respectively. Despite their moderate surface areas, these values indicated that functional groups within the polymer structures, including amides, amide-ethers, and amide-sulfones, played a … |
| Anahtar Kelimeler |
| Adsorption | Carbon dioxide | Friedel-Crafts | Hyper crosslinking | Polyaramids |
Science Direct
CO2 adsorption performance of novel polyaramid-based hyper-crosslinked polymers synthesized by the Friedel-Crafts
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 3 |
| Google Scholar | 3 |