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New hyper-crosslinked polymers for enhanced CO2 adsorption: Synthesis and characterization    
Yazarlar (1)
Dr. Öğr. Üyesi Kutalmış GÖKKUŞ Dr. Öğr. Üyesi Kutalmış GÖKKUŞ
Kastamonu Üniversitesi, Türkiye
Devamını Göster
Özet
In this study, new hyper-crosslinked polymers (HCPs) were synthesized with 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) and p-naphtholbenzeine (NB) with different ratios of 4,4′-bis(chloromethyl)-1,1′-biphenyl (BCMBP) through the Fridel-Crafts (FC) method. The polymers were thoroughly characterized by Fourier-transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area analysis, thermogravimetric analysis (TGA), and x-ray diffraction (XRD) confirming the successful synthesis of HCP-PTCDAs and hyper crosslinked p-naphtholbenzein polymers (HCP-NBs). BET analysis revealed that the maximum surface areas of HCP-PTCDA and HCP-NB were 962 m2 g−1 and 665.4 m2 g−1, respectively. The maximum pore volumes of HCP-PTCDA and HCP-NB were 1.26 cm3 g−1 and 1.90 cm3 g−1, respectively. The enhanced surface area and pore volume of HCP-PTCDAs were attributed to the lack of conformational changes in PTCDA during synthesis. The maximum CO2 adsorption capacities of the two polymers were obtained with HCP-PTCDA/20 and HCP-NB/5 (at 273 K and 1 bar: 2.75 mmol g−1 and 3.28 mmol g−1, respectively). Although the surface area of HCP-NB/5 was three times lower than HCP-PTCDA/20, it showed higher CO2 adsorption performance. Accordingly, these results revealed that pore volume and size distribution were one of the most determining parameters in CO2 adsorption. Compared with the literature, the improved CO2 adsorption performance, especially that of HCP-NB/5, showed that these polymers had relatively high potential.
Anahtar Kelimeler
Adsorption | Carbon dioxide | Friedel-Crafts | Gas capture | Hyper crosslinked polymers | Porous materials
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Sustainable Chemistry and Pharmacy
Dergi ISSN 2352-5541 Wos Dergi Scopus Dergi
Dergi Grubu Q2
Makale Dili İngilizce
Basım Tarihi 06-2025
Cilt No 45
Sayı 1
Doi Numarası 10.1016/j.scp.2025.102015
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
New hyper-crosslinked polymers for enhanced CO2 adsorption: Synthesis and characterization

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