Cobalt(II) and Cadmium(II) Metal–Organic Framework with Benzene-1,3,5-tricarboxylate and Viologen Guest: Stimuli-Responsive Photochromism, Volatile Amine Detection, and Hydrogen Generation
Yazarlar (3)
Ferihan Tataş Coşkun
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Doç. Dr. Kutalmış GÖKKUŞ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | ACS Omega (Q2) | ||
| Dergi ISSN | 2470-1343 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 04-2025 |
| Cilt / Sayı / Sayfa | 10 / 16 / 16938–16951 | DOI | 10.1021/acsomega.5c01484 |
| Makale Linki | https://doi.org/10.1021/acsomega.5c01484 | ||
| UAK Araştırma Alanları |
Hava Kirliliği ve Kontrolü
Temiz Üretim Teknolojileri
Su Kirliliği ve Kontrolü
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| Özet |
| Two Co(II) and Cd(II) coordination polymers, {(Me2bipy)[Co5(btc)3(Hbtc)(OH)]·2DMF·9H2O}n (CoMOF) and {(Me2bipy)[Cd2(μ4-btc)2]}n (OGU-2), were synthesized and characterized using IR spectroscopy, elemental analysis, and powder and single-crystal X-ray diffraction techniques. The Cd1 ion is seven-coordinated, adopting a distorted monocapped trigonal prismatic geometry (CdO7). OGU-2 exhibits a 3D porous framework with a rare flu-3,6-C2/c topology. The framework contains one-dimensional channels along the c axis with dimensions of approximately 10 × 10 Å2. The photochromic behavior of OGU-2 was investigated, revealing excellent chromic properties in response to multiple external stimuli, including UV light, temperature, and organic amines. CoMOF, a coordination polymer reported previously, along with OGU-2, was evaluated as a catalyst for hydrogen gas production via the methanolysis … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 3 |
| Scopus | 3 |
| Google Scholar | 3 |