Removal of AG 25 dye from aqueous solutions and treatment of real tannery wastewater by reusable magnetic iron oxide nanoparticles loaded with pomegranate pomace extract
 
Yazarlar (9)
Ahlem Khelali Université De Batna 1, Cezayir
Fatiha Benmahdi Université De Batna 1, Cezayir
Derradji Sahnoune Ptapc, Cezayir
Khettaf Sami Université De Batna 1, Cezayir
Gül Gülenay Hacıosmanoğlu Marmara Üniversitesi, Türkiye
Sumia Akram University Of Education, Pakistan
Doç. Dr. Kaan IŞINKARALAR Kastamonu Üniversitesi, Türkiye
Dwi Siswanta
Universitas Gadjah Mada, Endonezya
Ahmad Hosseini-Bandegharaei Semnan University, İran
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Environmental Research (Q1)
Dergi ISSN 0013-9351 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 08-2025
Cilt / Sayı / Sayfa 279 / 1 / 121744–0 DOI 10.1016/j.envres.2025.121744
Makale Linki https://doi.org/10.1016/j.envres.2025.121744
Özet
This study developed reusable magnetite iron oxide nanoparticles (Fe3O4@PGP-NPs) coated with pomegranate pomace extract (PGP) for the removal of Acid Green 25 (AG 25) dye and treatment of real tannery wastewater. The nanoparticles were characterized using FTIR, UV–Vis, XRD, FESEM/EDX, VSM, and BET techniques, revealing spherical Fe3O4 NPs with an average diameter of 20.30 nm, a BET surface area of 69 m2/g, and a magnetization value of 42.41 emu/g. Optimization via RSM-CCD identified optimal adsorption conditions: Fe3O4@PGP-NPs dosage of 2.2 g/L, contact time of 88 min, and dye concentration of 200 mg/L, achieving 99 % removal efficiency. Adsorption followed the Langmuir model, with a monolayer capacity of 213 mg/g, and pseudo-second-order kinetics. Thermodynamic analysis confirmed the process was spontaneous and endothermic. When applied to tannery wastewater, Fe3O …
Anahtar Kelimeler
Acid green 25 dye | Green synthesis | Magnetite iron oxide nanoparticles | Nanoadsorbent | Optimization | Pomegranate pomace waste | Tannery wastewater treatment