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Superiority of Modified Polymeric Membrane with Nanomaterial on Temperature and Mechanical Stability and Application in Industrial Waste Water       
Yazarlar
Canan Onac
Ahmet Kaya
Pamukkale Üniversitesi, Türkiye
Necip Atar
Pamukkale Üniversitesi, Türkiye
Prof. Dr. İzzet ŞENER Prof. Dr. İzzet ŞENER
Kastamonu Üniversitesi, Türkiye
Hamza Korkmaz Alpoğuz
Pamukkale Üniversitesi, Türkiye
Özet
In this paper, we investigated the superiotires of carbon-based nanomaterial polymer inclusion membrane (PIM-GO) against to polymer inclusion membrane and removed Cr(VI), a highly toxic element typically used in chromate conversion coating in the plating industry, from the chrome plating water by using a PIM-GO modified with graphene oxide (GO), which strengthens the mechanical structure and permeability of PIMs. We performed experiments to investigate the membrance performance and structural ability ofthe PIM-GO, and lastly compared its performance to that of the PIM. We observed the PIM-GO's high selectivity and recovery (96.83%) in the removal of Cr(VI). GO added to the membrane structure caused a visible increase in the rate constant, permeability and flux.The PIM-GO affords opportunities to work with a wider range of pH levels, changes of which in membrane-based experiments with unmodified PIM shave caused significant decreases in flux and permeability. The ease of use, applicability, high permeability of the PIM-GO at high temperatures afford significant advantages over the unmodified membrane as well. The results of this study can aid the development of next-generation membranes with increased mechanical stability, the resistance to multilayered GO membranes, and the use of the membranes in industrial applications. Moreover, the high transport efficiency of the PIM-GO at temperatures exceeding room temperature is evidence of the improved thermal stability of the PIM-GO. In effect, our findings can inform the production of new membranes with increased mechanical stability, membrane lifetime, and usability in industrial applications.
Anahtar Kelimeler
Chrome plating water | nanomaterial | polymeric membrane | graphane oxide | kinetic
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
Dergi ISSN 2162-8769
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 01-2020
Cilt No 9
Sayı 6
Sayfalar 61019 / 0
Doi Numarası 10.1149/2162-8777/aba725
Makale Linki https://iopscience.iop.org/article/10.1149/2162-8777/aba725