| Yazarlar |
Prof. Dr. Nesrin ŞENER
Kastamonu Üniversitesi, Türkiye |
Prof. Dr. İzzet ŞENER
Pamukkale Üniversitesi, Türkiye |
Serkan Yavuz
Gazi Üniversitesi, Türkiye |
|
Fikret Karcı
Pamukkale Üniversitesi, Türkiye |
| Özet |
| In this study, 20 novel disazo dyes containing pyrazole derivatives were synthesized by a convenient method. Diazotized aniline and some aniline derivatives were reacted with malononitrile to give 2-arylazomalononitrile derivatives 1(a-e). The synthesized 2-arylazomalononitrile derivatives were reacted with hydrazine and phenyl hydrazine to afford the corresponding 3,5-diamino-4-arylazo-1 H-pyrazole 2(a-e) and 3,5-diamino-4-arylazo-1-phenylpyrazole 3(a-e). Diazotized compounds of 2(a-e)and 3(a-e) reacted with ethylacetoacetate to give 4-arylazo-3-amino-1 H-pyrazole-5-ylazo-ethylacetoacetate 4(a-e) and 4-arylazo-3-amino-1-phenylpyrazole-5-ylazo-ethylacetoacetate 7(ae). The obtained 4(a-e) and 7(a-e) were reacted with hydrazine and phenyl hydrazine to give disazo dyes 5(a-e), 6(a-e), 8(a-e) and 9(a-e), respectively. The synthesized disazo dyes were characterized by spectroscopic techniques as well as elemental analysis. The solvatochromic behaviours of these dyes in various solvents were examined. Acid-base effects on the absorption maxima of the dyes were also reported. Antimicrobial activities of the synthesized novel disazo dyes were investigated. |
| Anahtar Kelimeler |
| Antimicrobial activity | Diazotization | Disazo dyes | Pyrazole | Pyrazolone | Solvatochromism |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Asian Journal of Chemistry |
| Dergi ISSN | 0970-7077 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2015 |
| Cilt No | 27 |
| Sayı | 8 |
| Sayfalar | 3003 / 3012 |
| Doi Numarası | 10.14233/ajchem.2015.18769 |
| Makale Linki | http://www.asianjournalofchemistry.co.in/user/journal/viewarticle.aspx?ArticleID=27_8_60 |
| Atıf Sayıları | |
| SCOPUS | 12 |
| Google Scholar | 18 |
| ResearchGate | 14 |
