Yazarlar |
Fikret Karcı
Pamukkale Üniversitesi, Türkiye |
Prof. Dr. İzzet ŞENER
Ankara Üniversitesi, Türkiye |
Hasalettin Deligöz
Pamukkale Üniversitesi, Türkiye |
Özet |
Twelve new azocalix[6]arenes (1-12) have been synthesized by linking o-, m-, p-chloroaniline, o-, m-, p-nitroaniline, o-, m-, p-toluidine, m-, p-anisidine and aniline to calix[6]arene through a diazo-coupling reaction. The prepared compounds were characterized based on UV-vis, FT-IR and 1H-NMR spectroscopic techniques as well as elemental analysis. The effect of varying pH and solvent upon the absorption ability of azocalixarenes substituted with electron-donating and electron-withdrawing groups at their o-, m-, p-position was examined. Observed results were compared with those found for unsubstituted azocalix[6]arenes. Concentration effects on the visible absorption maxima of the dyes are also reported. © 2004 Elsevier Ltd. All rights reserved. |
Anahtar Kelimeler |
Absorption spectra | Azocalix[6]arenes | Calixarene | Calixarene dyes | Diazo-coupling reaction | Solvent effect | Substituent effect |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | DYES AND PIGMENTS |
Dergi ISSN | 0143-7208 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 08-2004 |
Cilt No | 62 |
Sayı | 2 |
Sayfalar | 131 / 140 |
Doi Numarası | 10.1016/j.dyepig.2003.11.017 |