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Azocalixarenes 2 synthesis characterization and investigation of theabsorption spectra of azocalix 6 arenes containing chromogenic groups        
Yazarlar (3)
Fikret Karcı
Pamukkale Üniversitesi, Türkiye
Prof. Dr. İzzet ŞENER Prof. Dr. İzzet ŞENER
Ankara Üniversitesi, Türkiye
Hasalettin Deligöz
Pamukkale Üniversitesi, Türkiye
Devamını Göster
Özet
Twelve new azocalix[6]arenes (1-12) have been synthesized by linking o-, m-, p-chloroaniline, o-, m-, p-nitroaniline, o-, m-, p-toluidine, m-, p-anisidine and aniline to calix[6]arene through a diazo-coupling reaction. The prepared compounds were characterized based on UV-vis, FT-IR and 1H-NMR spectroscopic techniques as well as elemental analysis. The effect of varying pH and solvent upon the absorption ability of azocalixarenes substituted with electron-donating and electron-withdrawing groups at their o-, m-, p-position was examined. Observed results were compared with those found for unsubstituted azocalix[6]arenes. Concentration effects on the visible absorption maxima of the dyes are also reported. © 2004 Elsevier Ltd. All rights reserved.
Anahtar Kelimeler
Absorption spectra | Azocalix[6]arenes | Calixarene | Calixarene dyes | Diazo-coupling reaction | Solvent effect | Substituent effect
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı DYES AND PIGMENTS
Dergi ISSN 0143-7208
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 08-2004
Cilt No 62
Sayı 2
Sayfalar 131 / 140
Doi Numarası 10.1016/j.dyepig.2003.11.017