Comparison of adsorption and selectivity characteristics for4 nitrophenol imprinted polymers prepared via bulk and suspensionpolymerization
Yazarlar (6)
Ridvan Say
Anadolu Üniversitesi, Türkiye
Prof. Dr. Arzu Ersöz Anadolu Üniversitesi, Türkiye
Prof. Dr. İzzet ŞENER Pamukkale Üniversitesi, Türkiye
Ayça Atilir
Anadolu Üniversitesi, Türkiye
Sibel Diltemiz
Anadolu Üniversitesi, Türkiye
Prof. Dr. Adil Denizli Hacettepe Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Separation Science and Technology
Dergi ISSN 0149-6395 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 11-2004
Kabul Tarihi Yayınlanma Tarihi 02-01-2005
Cilt / Sayı / Sayfa 39 / 15 / 3471–3484 DOI 10.1081/SS-200028939
Makale Linki https://www.tandfonline.com/doi/full/10.1081/SS-200028939
UAK Araştırma Alanları
Organik Kimya
Özet
This manuscript describes a method for the selective removal of phenolic compounds from aqueous medium by imprinted polymers, which is the noncovalent approach based on both hydrogen bonding and hydrophobic interaction. These imprinted polymers were prepared by both bulk polymerization (IP1) and suspension polymerization (IP2) of methacryloylantipyrine (MAAP) in the presence of azobisisobutyronitrile (AIBN) as an initiator and cross‐linking EGDMA and was imprinted with 4‐nitrophenol. The effect of polymerization technique (bulk and suspension) on the adsorption and selectivity of phenolics was investigated. The maximum adsorption capacities of these IP1 and IP2 polymers were 25.9 and 27.6 mg/g for 4‐nitrophenol, respectively. It was observed that the 4‐nitrophenol binding capacity decreased with increasing pH. The selectivity experiments showed that the polymer prepared via suspension …
Anahtar Kelimeler
Adsorption of phenol | Bulk and suspension polymerization | Molecularly imprinted polymer (MIP) | Phenol