An approach to the synthesis of chemically modified bisazocalix 4 arenes and their extraction properties
Yazarlar (5)
Prof. Dr. Tahir Tilki Süleyman Demirel Üniversitesi, Türkiye
Prof. Dr. İzzet ŞENER Pamukkale Üniversitesi, Türkiye
Prof. Dr. Fikret Karcı Pamukkale Üniversitesi, Türkiye
Ahmet Gülce
Süleyman Demirel Üniversitesi, Türkiye
Hasalettin Deligöz
Pamukkale Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Tetrahedron
Dergi ISSN 0040-4020 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2005
Kabul Tarihi Yayınlanma Tarihi 01-10-2005
Cilt / Sayı / Sayfa 61 / 40 / 9624–9629 DOI 10.1016/j.tet.2005.07.078
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0040402005012883
UAK Araştırma Alanları
Organik Kimya
Özet
Bisazocalix[4]arenes [N,N′-bis(5-azo-25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene)benzene (), N,N′-bis(5-azo-25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene)biphenyl () and N,N′-bis(5-azo-25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene)-2,2′-dinitro biphenyl ()] have been synthesized from 25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene by diazocoupling with the corresponding aromatic diamines (p-phenylenediamine, 4,4′-diamino biphenyl and 4,4′-diamino-2,2′-dinitrobiphenyl). Extraction studies of bisazocalix[4]arenes , , and show no difference in their extraction behavior and selectivity, whereas azocalix[4]arenes are a poor extractant for heavy metal cations. The absorption spectra of the prepared bisazocalix[4]arenes are discussed, both the effect of varying pH and solvent upon the absorption ability of bisazocalix[4]arenes.
Anahtar Kelimeler
Absorption properties | Bisazocalix[4]arenes | Calix[n]arenes | Diazocoupling reaction | Solvent extraction
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 33
Scopus 34
Google Scholar 44
An approach to the synthesis of chemically modified bisazocalix 4 arenes and their extraction properties

Paylaş