Carrier mediated transport of Hg II through bulk and supported liquidmembranes
Yazarlar (3)
H. Korkmaz Alpoguz
Pamukkale Üniversitesi, Türkiye
Doç. Dr. Ahmet Kaya Pamukkale Üniversitesi, Türkiye
Prof. Dr. İzzet ŞENER Pamukkale Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Macromolecular Science Part A Pure and Applied Chemistry
Dergi ISSN 1060-1325 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2007
Kabul Tarihi Yayınlanma Tarihi 01-08-2007
Cilt / Sayı / Sayfa 44 / 10 / 1061–1068 DOI 10.1080/10601320701519559
Makale Linki http://www.tandfonline.com/doi/full/10.1080/10601320701519559
UAK Araştırma Alanları
Organik Kimya
Özet
The transport of Hg (II) ions from an aqueous solution into an aqueous receiving solution through bulk and supported liquid membranes containing a calix[4]arene derivative 1 as a carrier was examined. The kinetic parameters of bulk liquid membrane studies were analyzed assuming two consecutive, irreversible first‐order reactions. The influence of temperature, stirring rate, carrier concentration and solvent on the kinetic parameters (k1, k2, Rm max, tmax, Jd max, Ja max) has also been investigated. The membrane entrance rate, k1, and the membrane exit rate, k2, increased with increasing temperature and stirring rate. The activation energy values are calculated as 4.87 and 48.63 kj mol−1 for extraction and reextraction, respectively. The values of calculated activation energy indicate that the process is diffusionally controlled by species. Also, the transport behavior of Hg2+ from aqueous solution through a flat …
Anahtar Kelimeler
Calixarenes | Liquid membrane | Transport kinetics | Transport of Hg (II)
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 12
Scopus 12
Google Scholar 11
Carrier mediated transport of Hg II through bulk and supported liquidmembranes

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