Role of Mg substitution in modulating defect-mediated magnetism and mechanical strength of Zn0.95Co0.05O systems
Yazarlar (6)
Doç. Dr. Elif AŞIKUZUN TOKEŞER Kastamonu Üniversitesi, Türkiye
G. Yildirim
Bolu Abant İzzet Baysal Üniversitesi, Türkiye
A. S. Ertürk
Adiyaman Üniversitesi, Türkiye
Prof. Dr. Özgür ÖZTÜRK Kastamonu Üniversitesi, Türkiye
T. Seydioglu
Kastamonu Üniversitesi, Türkiye
C. Terzioglu
Bolu Abant İzzet Baysal Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Sol Gel Science and Technology (Q1)
Dergi ISSN 0928-0707 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 07-2025
Cilt / Sayı / Sayfa 115 / 3 / 1694–1714 DOI 10.1007/s10971-025-06882-7
Makale Linki https://doi.org/10.1007/s10971-025-06882-7
UAK Araştırma Alanları
Süper İletken Malzemeler Yarı İletken Malzemeler Kompozit Malzemeler
Özet
This study investigates the structural, magnetic, and mechanical modifications induced by partial Mg/Zn substitution in Zn0.95Co0.05O diluted magnetic semiconductor (DMS) systems prepared by the sol-gel method. A combination of X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), and Vickers microhardness (Hv) testing is employed to assess the impact of Mg incorporation. Experimental and computational results confirm the successful substitution of Mg²⁺ ions into the ZnCoO lattice without forming secondary phases. XRD analyses reveal a slight reduction in crystallite size, varying from 37.62 nm to 36.48 nm, attributable to the differences in ionic radius and electronegativity between Mg²⁺ and Zn²⁺ ions. Mg addition enhances crystallinity, interface state formation, and atomic-scale interactions, while promoting quantum confinement effects. SEM observations indicate that Mg/Zn substitution significantly influences particle size, surface morphology, and oxide layer thickness. Increasing Mg content improves grain coupling and surface uniformity through strengthened interfacial interactions. Microhardness results show that Mg incorporation improves mechanical stability by limiting crack propagation, enhancing grain boundary couplings, and minimizing stored internal strain energy. Magnetic measurements indicate that all samples exhibit predominantly paramagnetic behavior with weak ferromagnetic features emerging at low temperatures. Low-temperature magnetization is attributed to defect-mediated ferromagnetic coupling, whereas high-temperature behavior follows Curie–Weiss paramagnetism. The Mg/Zn substitution alters electronic structure and oxygen vacancy distribution, modulating exchange interactions. Small coercivity values (230 Oe in ZFC and 570 Oe in FC) and vertical M–H loop shifts at 5 K suggest diluted antiferromagnetism rather than conventional exchange bias effects. Additionally, creep analysis from loading–unloading curves confirms that increasing Mg content lowers the creep rate, with the ZnO: Mg (5%) sample exhibiting the best mechanical resilience. In conclusion, Mg substitution significantly enhances the structural, magnetic, and mechanical performance of ZnCoO matrices, making them more favorable for controlled paramagnetic applications than room-temperature spintronic technologies.
Anahtar Kelimeler
Coupling strength | Diluted magnetic semiconductor | Mg/Zn substitution | Paramagnetism
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Scopus 2
Role of Mg substitution in modulating defect-mediated magnetism and mechanical strength of Zn0.95Co0.05O systems

Paylaş

İletişim
  • Kastamonu Üniversitesi Rektörlüğü, Kuzeykent Kampüsü, Merkez/Kastamonu
  • unis@kastamonu.edu.tr 03662801000
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