| Yazarlar (6) |
Dr. Öğr. Üyesi Kutalmış GÖKKUŞ
Kastamonu Üniversitesi, Türkiye |
Ayşegül Özbal
Eskişehir Osmangazi Üniversitesi, Türkiye |
Prof. Dr. Mahmut GÜR
Kastamonu Üniversitesi, Türkiye |
|
Salih Alper Akalın
Dokuz Eylül Üniversitesi, Türkiye |
|
Hazal Sebli
Kastamonu Üniversitesi, Türkiye |
|
Vural Bütün
Eskişehir Osmangazi Üniversitesi, Türkiye |
| Özet |
| Four novel hyper-crosslinked polymers (HCP-1 to HCP-4) were synthesized via Friedel–Crafts alkylation using 4,4′-bis(chloromethyl)-1,1′-biphenyl as the crosslinker and various aromatic monomers including triphenylphosphine (TPP). These polymers were designed as metal-free catalysts for hydrogen generation via sodium borohydride methanolysis. Comprehensive characterization using FT-IR, XPS, BET, TGA, SEM, and zeta potential analyses confirmed that the materials possess thermally stable, porous networks with irregular morphologies and distinct surface charges. Under practical conditions, HCP-3 exhibited the highest catalytic activity with a hydrogen generation rate of 9857 mL H2 min−1 g−1 at 303.15 K and the lowest activation energy (Ea = 32.0 kJ mol−1). At elevated temperature (333.15 K), HCP-2 achieved the highest activity (37,200 mL H2 min−1 g−1), reflecting the strong influence … |
| Anahtar Kelimeler |
| Hydrogen generation | Hyper-crosslinked polymers | NaBH4 methanolysis | Triphenylphosphine | Zeta potential |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Reactive and Functional Polymers |
| Dergi ISSN | 1381-5148 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q1 |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2025 |
| Cilt No | 217 |
| Sayı | 1 |
| Sayfalar | 106480 / 0 |
| Doi Numarası | 10.1016/j.reactfunctpolym.2025.106480 |
| Makale Linki | https://doi.org/10.1016/j.reactfunctpolym.2025.106480 |
| Atıf Sayıları |
