Increasing the Performance of Cathode Material in Alkaline (Li, Na and K) Ion Battersis: Synthesis and Characterization

Bagheri, Samira; MONAJJEMI, Majıd; Ziglari, Alireza; Taghvamanesh, Afshin

doi:10.1134/S1990793121090049

Increasing the Performance of Cathode Material in Alkaline (Li, Na and K) Ion Battersis: Synthesis and Characterization

Yazarlar (4)

Samira Bagheri
Islamic Azad University, Central Tehran Branch, İran

Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Central Tehran Branch, İran

Alireza Ziglari Islamic Azad University, Central Tehran Branch, İran

Afshin Taghvamanesh
Islamic Azad University, Central Tehran Branch, İran

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Russian Journal of Physical Chemistry B
Dergi ISSN	1990-7931 Wos Dergi Scopus Dergi
Makale Dili	İngilizce	Basım Tarihi	08-2021
Cilt / Sayı / Sayfa	15 / 1 / –	DOI	10.1134/S1990793121090049

Özet

Abstract: The purpose of this study is to find a ternary solid solution of nickel, magnesium, manganese in the alkaline-based cathode material (Na, Li) replacement with LiCoO2 that is too much expensive and toxic. Samples from the proposed {[(1–x–y) LiNi0.7Co0.3 (Al and Mg doped)] O2} system were synthesized using the sol-gel method. Stoichiometric weights of the LiNO3, Mg (NO3)2⋅6H2O, Mn (Ac)2⋅4H2O, Co(Ac)2⋅4H2O, Ni(NO3)2⋅6H2O as starting materials of lithium, magnesium, manganese , cobalt and nickel, in 28 samples of {[(1–x–y) LiNi0.7Co0.3 (Al and Mg doped)] O2}, respectively. We exhibited “Li1.167Ni0.117Co0.699Al0.017Mn0.167O2” is the best composition for cathode material. Obviously, the used weight of cobalt in these samples is lower compared with LiCoO2 that is an advantage in view point of cost in this study. With the same method we used (1–x–y) LiNi0.7 Co0.2Mg0.1, xLi2MnO3, yLiCoO2 composites and five samples have been found with the best conditions in viewpoints of capacity and cyclability. Among these samples with Li1.333Ni0.1Mg0.017Co0.551Mn0.333O2 structure is the best sample of those 28 compositions including Mg doped position. Charge-discharge characteristics of the mentioned cathode materials were investigated by performing cycle tests in the range of 2.4–4.6 V. Our results confirmed, although these kind systems can help for removing the disadvantage of cobalt which mainly is its cost and toxic, the performance of these kind systems are similar to LiCoO2 or NaCoO2 cathode materials.

Anahtar Kelimeler

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	7
Scopus	7

Increasing the Performance of Cathode Material in Alkaline (Li, Na and K) Ion Battersis: Synthesis and Characterization

Dergi Adı	Russian Journal of Physical Chemistry B
Yayıncı	Pleiades Publishing
Açık Erişim	Hayır
ISSN	1990-7931
E-ISSN	1990-7923
CiteScore	2,6
SJR	0,244
SNIP	0,763

Increasing the Performance of Cathode Material in Alkaline (Li, Na and K) Ion Battersis: Synthesis and Characterization

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