Amino Functionalized Nano Fe3O4@SiO2 as a Magnetically Green Catalyst for the One-Pot Synthesis of Spirooxindoles Under Mild Conditions
Yazarlar (4)
Fatemeh Alemi-Tameh
Islamic Azad University, Science And Research Branch, İran
Javad Safaei-Ghomi
Islamic Azad University, Science And Research Branch, İran
Mohammad Mahmoudi-Hashemi Islamic Azad University, Science And Research Branch, İran
Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Science And Research Branch, İran
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Polycyclic Aromatic Compounds (Q3)
Dergi ISSN 1040-6638 Dergi Bilgileri (2018)
Makale Dili İngilizce Basım Tarihi 01-2018
Cilt / Sayı / Sayfa 38 / 3 / 199–212 DOI 10.1080/10406638.2016.1179650
Makale Linki http://www.scopus.com/inward/record.url?eid=2-s2.0-85004024913&partnerID=MN8TOARS
UAK Araştırma Alanları
Özet
(3-Aminopropyl)-triethoxysilane attached to Fe3O4@SiO2 nanoparticles has been characterized by powder X-ray diffraction, vibrating sample magnetometer, scanning electronic microscope, transmission electron microscope, energy dispersive X-ray, thermal gravimetric analysis, and Fourier transform infrared spectroscopy. The prepared nanoparticles employed as a heterogeneous catalyst in the synthesis of spirooxindoles derivatives in one-pot four-component reactions of isatin, methyl cyanoacetate or malononitrile, hydrazine hydrate, and ethyl acetoacetate. Amino-functionalized magnetic nanoparticles showed high catalytic activity in mild reaction conditions and excellent yields of products in short reaction times. Also, this nanocatalyst can be easily recovered by a magnet and reused for subsequent reactions for at least 5 times without noticeable loss in catalytic activity.
Anahtar Kelimeler
Core–shell | Fe3O4@SiO2–NH2 | multicomponent reactions | one-pot synthesis | spirooxindoles