Determination of thermodynamic properties of aqueous mixtures of MgCl2 and Mg(NO3)2 by the potentiometric method at T=298.15

Pournaghdy, Mohammad; Giahi, Masoud; Bagherinia, Mohammad A.; MONAJJEMI, Majıd; Aghaie, Hossein; Aghaie, Mehran

doi:10.1016/j.fluid.2010.11.010

Determination of thermodynamic properties of aqueous mixtures of MgCl₂ and Mg(NO₃)₂ by the potentiometric method at T=298.15

Yazarlar (6)

Mohammad Pournaghdy Islamic Azad University, Science And Research Branch, İran

Masoud Giahi Islamic Azad University, Lahijan Branch, İran

Mohammad A. Bagherinia Islamic Azad University, Lahijan Branch, İran

Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Science And Research Branch, İran

Hossein Aghaie Islamic Azad University, Science And Research Branch, İran

Mehran Aghaie Islamic Azad University, North Tehran Branch, İran

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Fluid Phase Equilibria
Dergi ISSN	0378-3812 Wos Dergi Scopus Dergi
Makale Dili	İngilizce	Basım Tarihi	02-2011
Cilt / Sayı / Sayfa	301 / 1 / 98–104	DOI	10.1016/j.fluid.2010.11.010
Makale Linki	http://www.scopus.com/inward/record.url?eid=2-s2.0-78650589594&partnerID=MN8TOARS

Özet

In this research, thermodynamic properties of the ternary electrolyte system (MgCl2+Mg(NO3)2+H2O) were investigated using a potentiometric method. The galvanic cell used had no liquid junction of type: Mg-ISE|MgCl2 (mA), Mg(NO3)2 (mB), H2O|Ag/AgCl. The measurements were performed at T=298.15K and at total ionic strengths from 0.001 to 8.000mol/kg for different series of salt ratios r=mMgCl2/mMg(NO3)2 =1.00, 2.50, 5.00, 7.50, 10.00 and 15.00. The PVC based magnesium ion-selective electrode (Mg-ISE) and the Ag/AgCl electrode used in this work were prepared in our laboratory and showed a reasonably good Nernst response. The Pitzer ion interaction model and Harned rule were used to illustrate the ternary electrolyte system investigated. The experimental results showed that both Pitzer model and Harned rule were suitable to be used satisfactorily to describe this ternary system. © 2010 Elsevier B.V.

Anahtar Kelimeler

Mg(NO3)2 | MgCl2 | Pitzer model | Potentiometric method | Thermodynamic properties

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	7
Scopus	9

Determination of thermodynamic properties of aqueous mixtures of MgCl₂ and Mg(NO₃)₂ by the potentiometric method at T=298.15

Dergi Adı	FLUID PHASE EQUILIBRIA
Yayıncı	Elsevier B.V.
Açık Erişim	Hayır
ISSN	0378-3812
E-ISSN	1879-0224
CiteScore	5,4
SJR	0,578
SNIP	0,996

Determination of thermodynamic properties of aqueous mixtures of MgCl2 and Mg(NO3)2 by the potentiometric method at T=298.15

Paylaş

Determination of thermodynamic properties of aqueous mixtures of MgCl₂ and Mg(NO₃)₂ by the potentiometric method at T=298.15