The Studies of Equilibrium and Thermodynamic Adsorption of Pb(II), Cd(II) and Cu(II) Ions from Aqueous Solution onto SWCNTs and SWCNT-COOH Surfaces
Yazarlar (5)
O. Moradi
Islamic Azad University, İran
K. Zare Islamic Azad University, Science And Research Branch, İran
Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Science And Research Branch, İran
M. Yari Islamic Azad University, Islamshahr Branch, İran
H. Aghaie Islamic Azad University, Science And Research Branch, İran
Makale Türü Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı Fullerenes Nanotubes and Carbon Nanostructures
Dergi ISSN 1536-383X Wos Dergi Scopus Dergi
Makale Dili İngilizce Basım Tarihi 01-2010
Cilt / Sayı / Sayfa 18 / 3 / 285–302 DOI 10.1080/15363831003783005
Makale Linki http://www.scopus.com/inward/record.url?eid=2-s2.0-77954288417&partnerID=MN8TOARS
Özet
The equilibrium and thermodynamics of Pb(II), Cd(II) and Cu(II) ions adsorption from aqueous solution onto single-walled carbon nanotube (SWCNT) and carboxylate group functionalized single-walled carbon nanotube (SWCNT-COOH) surfaces were studied by atomic absorption spectroscopy. The effect of contact time, pH, initial concentration of ion, ionic strength and temperature on the adsorption of ion was investigated. The results indicated that Langmuir model fits adsorption isotherm data better than the Freundlich model. The results also demonstrated that SWCNT-COOH surfaces can more effectively adsorb mentioned ions than a SWCNT surface. Maximum adsorption capacities (qm) for Pb(II), Cu(II) and Cd(II) ions onto SWCNT-COOH were obtained as 96.02, 77.00 and 55.89 mg/g, respectively, and by SWCNTs as 33.55, 24.29 and 24.07 mg/g, respectively. Thermodynamic parameters values showed that the adsorption of ions on SWCNT-COOH and SWCNTs at 283-313 K is spontaneous and endothermic. Copyright © 2010 Taylor & Francis Group, LLC.
Anahtar Kelimeler
Adsorption | Heavy metal ions | Isotherm models | Single-walled carbon nanotube | Thermodynamic functions