Tin(II)-selective membrane potentiometric sensor using a crown ether as neutral carrier
Yazarlar (6)
H. Aghaie
Islamic Azad University, İran
M. Giahi Islamic Azad University, İran
Prof. Dr. Majıd MONAJJEMI Islamic Azad University, İran
M. Arvand University Of Guilan, İran
G. H. Nafissi Kharazmi University, İran
M. Aghaie
Islamic Azad University, North Tehran Branch, İran
Makale Türü Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı Sensors and Actuators B Chemical
Dergi ISSN 0925-4005 Wos Dergi Scopus Dergi
Makale Dili İngilizce Basım Tarihi 06-2005
Cilt / Sayı / Sayfa 107 / 2 / 756–761 DOI 10.1016/j.snb.2004.12.010
Makale Linki http://www.scopus.com/inward/record.url?eid=2-s2.0-18544384358&partnerID=MN8TOARS
Özet
A PVC membrane Sn(II)-ion-selective electrode has been constructed using dibenzo-18-crown-6 (DB18C6) as membrane carrier. The sensor shows a near Nernstian response for Sn(II) ions over a concentration range from 1.0 × 10-6 to 1.0 × 10-2 M with a slope of 27.5 ± 0.6 mV per concentration decade in an acidic solution (pH = 1). The limit of detection was 8.0 × 10-7 M. It has a response time of <15 s and can be used for at least 3 months without any divergence in potentials. The proposed membrane electrode revealed very good selectivity for Sn(II) ions over a wide variety of other cations and could be used in acidic media. The isothermal temperature coefficient of this electrode amounted to 0.0012 V/°C. The stability constant (log Ks) of the Sn(II)-DB18C6 complex was determined at 25 °C by potentiometric titration in mixed aqueous solution. It was used as indicator electrode in potentiometric determination of Sn(II) ion in real sample. © 2004 Elsevier B.V. All rights reserved.
Anahtar Kelimeler
Crown ether | Potentiometric sensor | PVC membrane | Tin(II)
Science Direct
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Web of Science 32
Scopus 39
Tin(II)-selective membrane potentiometric sensor using a crown ether as neutral carrier

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