Complexation of alkali metal ions with di and tri-propyl ether of P-tert-butyl-calix[4]arenes: ab initio approach
Yazarlar (4)
Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Science And Research Branch, İran
Afsaneh Amiri Islamic Azad University, Science And Research Branch, İran
Farrakhan Gharib Islamic Azad University, Science And Research Branch, İran
Karim Zare Islamic Azad University, Science And Research Branch, İran
| Makale Türü |
Özgün Makale
(ESCI dergilerinde yayınlanan tam makale)
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| Dergi Adı | Main Group Metal Chemistry | ||
| Dergi ISSN | 0792-1241 Wos Dergi Scopus Dergi | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2004 |
| Cilt / Sayı / Sayfa | 27 / 2 / 107–112 | DOI | 10.1515/MGMC.2004.27.2.107 |
| Makale Linki | http://www.scopus.com/inward/record.url?eid=2-s2.0-4544241698&partnerID=MN8TOARS | ||
| Özet |
| The binding selectivity of di- and tri-propyl ether of p-tert-butyl- calix[4]arenes (1 and 2) with alkali metal ion have been investigated and the structure and complexation energies of a simplified host with alkali metal ions also have been optimized by ab initio HF/6-31G quantum mechanics method. The binding selectivity of di- and tri-propyl ether of P-tert-butyl-calix[4]arenes (1 and 2) towards alkali cations, based on the stability constant values of the formed complexes, is in the order of Cs+ > Li+ > Na+ > Rb+ > K+ and Cs+ > Li+ > Rb+ > Na+ > K+, respectively. On the basis of the complex's enthalpy ΔH |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 1 |
| Scopus | 2 |