Interaction of Tl<SUP>+3</SUP> with mononucleotides: metal ion binding and sugar conformation

Nafisi, Sh; Mohajerani, N.; Hadjiakhoondi, A.; MONAJJEMI, Majıd; Garib, F.

doi:10.1016/S0022-2860(00)00918-2

Interaction of Tl⁺³ with mononucleotides: metal ion binding and sugar conformation

Yazarlar (5)

Sh Nafisi Islamic Azad University, Central Tehran Branch, İran

N. Mohajerani Welfare Sciences University, İran

A. Hadjiakhoondi University Of Tehran, İran

Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Central Tehran Branch, İran

F. Garib Islamic Azad University, Central Tehran Branch, İran

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Journal of Molecular Structure
Dergi ISSN	0022-2860 Wos Dergi Scopus Dergi
Makale Dili	İngilizce	Basım Tarihi	05-2001
Cilt / Sayı / Sayfa	562 / 1 / 35–43	DOI	10.1016/S0022-2860(00)00918-2
Makale Linki	http://www.scopus.com/inward/record.url?eid=2-s2.0-0035795768&partnerID=MN8TOARS

Özet

The interaction of Tl³⁺ with sodium salts of adenosine-5′-monophosphate (5′-AMP), guanosine-5′-monophosphate (5′-GMP), cytidine-5′-monophosphate (5′-CMP), thymidine 5′-monophosphate (5′-dTMP) in ratios 1 and 2 have been studied in neutral pH. The solid complexes were isolated and characterized by Fourier transform infrared (FTIR) and ¹H NMR spectroscopy. In the Tl2(AMP)3, Tl³+ binds directly to N-7 and indirectly to the N-1 position of the pyrimidine ring and phosphate group with sugar moiety in C2′-endoanti. The crystalline salt of Tl2(GMP)3 show direct Tl-N-7 and Tl-PO3 (inner-sphere) binding. The conformation of ribose moiety in Tl2(GMP)3 is C3′-endoanti. In the Tl2(CMP)3, Tl³⁺ bind directly to N-3 and PO3^2- (inner-sphere). The conformation of ribose moiety in Tl2(CMP)3 is C2′-endoanti. In the Tl2(dTMP)3, Tl³⁺ bind indirectly to carbonyl group. The sugar moiety in Tl2(dTMP)3 is C3′-endoanti. © 2001 Elsevier Science B.V.

Anahtar Kelimeler

Metal ion | Mononucleotides | Sugar conformation

Science Direct

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	11
Scopus	13

Interaction of Tl⁺³ with mononucleotides: metal ion binding and sugar conformation

Dergi Adı	Journal of Molecular Structure
Yayıncı	Elsevier B.V.
Açık Erişim	Hayır
ISSN	0022-2860
E-ISSN	1872-8014
CiteScore	8,0
SJR	0,628
SNIP	0,999

Interaction of Tl+3 with mononucleotides: metal ion binding and sugar conformation

Paylaş

Interaction of Tl⁺³ with mononucleotides: metal ion binding and sugar conformation