Complexation of asparagine and glutamine by dioxovanadium

Gharib, F; MONAJJEMI, Majıd; Ketabi, S; Zoroufi, F

Complexation of asparagine and glutamine by dioxovanadium

Yazarlar (4)

F Gharib Shahid Beheshti University, İran

Prof. Dr. Majıd MONAJJEMI Islamic Azad University, Science And Research Branch, İran

S Ketabi Kharazmi University, İran

F Zoroufi University Of Science And Technology, İran

Makale Türü	Özgün Makale (ESCI dergilerinde yayınlanan tam makale)
Dergi Adı	Russian Journal of Inorganic Chemistry
Dergi ISSN	0036-0236 Wos Dergi Scopus Dergi
Makale Dili	İngilizce	Basım Tarihi	03-2001
Cilt / Sayı / Sayfa	46 / 3 / 363–366	DOI	–
Makale Linki	http://www.scopus.com/inward/record.url?eid=2-s2.0-0035761928&partnerID=MN8TOARS

Özet

The complexation of pervanadyl ion (VO⁺ 2) with L-asparagine and L-glutamine has been investigated by spectrophotometric measurements in aqueous solution at an ionic strength of 0.15 mol 1^-1 (NaClO4) and 25 ± 0.1°C in the pH range 1.3-10.3 with high ligand-to-metal ratios. The stability constants of the formed complexes and their stoichiometries are given and interpreted. The logarithms of the cumulative stability constant βxyz of the [(H)x(oxometal)y(amino acid)z] complex are logβ101 = 8.80 ± 0.08, logβ011 = 9.47 ± 0.10, and logβ012 = 14.57 ± 0.15 for asparagine and logβ101 = 9.05 ± 0.10, logβ011 = 9.54 ± 0.10, and logβ012 = 14.81 ± 0.15 for glutamine. The coordination mode of the ligands in their protonated and deprotonated complexes is discussed on the basis of these parameters.

Anahtar Kelimeler

BM Sürdürülebilir Kalkınma Amaçları

Atıf Sayıları
Web of Science	6
Scopus	6
Scopus	3

Dergi Adı	RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Yayıncı	Pleiades Publishing
Açık Erişim	Hayır
ISSN	0036-0236
E-ISSN	1531-8613
CiteScore	3,0
SJR	0,270
SNIP	0,518

Complexation of asparagine and glutamine by dioxovanadium

Paylaş