Fluoranthene-based metal-free hyper-crosslinked polymers for NaBH4 methanolysis: mechanistic role of surface-charge effects
Yazarlar (6)
Doç. Dr. Kutalmış GÖKKUŞ Kastamonu Üniversitesi, Türkiye
Arş. Gör. Aysegul Ozbal Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Mahmut GÜR Kastamonu Üniversitesi, Türkiye
S. Alper Akalin
Dokuz Eylül Üniversitesi, Türkiye
Dokuz Eylül Üniversitesi, Türkiye
U. Merve Senturan
Kastamonu Üniversitesi, Türkiye
Kastamonu Üniversitesi, Türkiye
Prof. Dr. Vural Bütün Eskişehir Osmangazi Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Fuel (Q1) | ||
| Dergi ISSN | 0016-2361 Dergi Bilgileri (2026) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-2026 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-10-2026 |
| Cilt / Sayı / Sayfa | 421 / 1 / 139061–0 | DOI | 10.1016/j.fuel.2026.139061 |
| Makale Linki | https://doi.org/10.1016/j.fuel.2026.139061 | ||
| UAK Araştırma Alanları |
Organik Kimya
Spektroskopi
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| Özet |
| Fluoranthene-based hyper-crosslinked polymers (HCPs) were synthesized via Friedel–Crafts alkylation and evaluated as metal-free catalysts for hydrogen generation through NaBH4 methanolysis. Despite moderate hydrogen-generation rates relative to some polymeric systems, the catalysts exhibited distinct structure–activity behavior that could not be explained by surface area or heteroatom content alone. Notably, HCP-4 achieved the highest hydrogen-generation rate (31,200 mL H2 min−1 gcat−1 at 333.15 K), whereas HCP-1 showed the lowest apparent activation energy (23.6 kJ mol−1), indicating decoupled kinetic and textural contributions. Zeta-potential analysis revealed pronounced reaction-induced modulation of surface charge, identifying interfacial electrostatics as a dominant mechanistic factor governing hydride activation. These findings demonstrate that π-conjugated polymer architecture and … |
| Anahtar Kelimeler |
| Friedel–Crafts alkylation | Hydrogen generation | Hyper-crosslinked polymers | Metal-free catalysis | NaBH4 methanolysis | Surface area |
Science Direct
Fluoranthene-based metal-free hyper-crosslinked polymers for NaBH4 methanolysis: mechanistic role of surface-charge effects
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 2 |
| Google Scholar | 4 |