Some new Schiff base derived thiosemicarbazones: Synthesis, spectroscopic characterization, and theoretical studies
Yazarlar (3)
Doç. Dr. Hasan Yakan Ondokuz Mayis Üniversitesi, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SCOPUS dergilerinde yayınlanan tam makale)
|
||
| Dergi Adı | Gumushane Universitesi Fen Bilimleri Dergisi | ||
| Dergi ISSN | 2146-538X | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2026 |
| Cilt / Sayı / Sayfa | 16 / 1 / 50–70 | DOI | 10.17714/gumusfenbil.1791390 |
| Makale Linki | https://doi.org/10.17714/gumusfenbil.1791390 | ||
| UAK Araştırma Alanları |
Fen Bilimleri ve Matematik
|
||
| Özet |
| A series of some new Schiff base-derived thiosemicarbazones (1–6) were synthesized from various aldehydes and N-(o-tolyl)hydrazinecarbothioamide. The thiosemicarbazide was prepared by the reaction of 1-isothiocyanato-2-methylbenzene with hydrazine monohydrate. The structures and purity of these compounds were confirmed using standard spectroscopic methods, including proton and carbon nuclear magnetic resonance (1H and 13C NMR), Fourier-transform infrared spectroscopy (FT-IR), and elemental analysis. The structural and electronic properties of the compounds were examined using Density Functional Theory (DFT) calculations, and their relationship to structural characterization was analysed and discussed. Additionally, the influence of substituent groups on both the electronic properties and activation behaviors of the compounds was explored. |
| Anahtar Kelimeler |
| DFT calculations | Schiff base | Structure elucidation | Thiosemicarbazones |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Google Scholar | 1 |