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Experimental and theoretical approaches on thermal and structural properties of Zn doped BSCCO glass ceramics      
Yazarlar
Haluk Koralay
Gazi Üniversitesi, Türkiye
Öznur Hiçyılmaz
Şükrü Çavdar
Gazi Üniversitesi, Türkiye
Prof. Dr. Özgür ÖZTÜRK
Kastamonu Üniversitesi, Türkiye
Prof. Dr. Ahmet Tolga TAŞÇI
Kastamonu Üniversitesi, Türkiye
Özet
Thermal properties of Cu-Zn partially substituted Bi1.8Sr2Ca2Cu3.2-xZnxO10+δ (x = 0, 0.1 and 0.5) glass-ceramic systems have been investigated with the help of a differential thermal analyzer (DTA) by using Johnson-Mehl-Avrami-Kolmogorov (JMAK) approximation. Non-isothermal crystallization kinetics of the samples has been tested. The calculated values of activation energy of crystallization (E) and Avrami parameter (n) ranged between 306.1 and 338.3 kJ·mol-1 and 1.29 and 3.59, respectively. Crystallization kinetics was compared following the partial substitution, before and after Zn doping of the sample. In addition, by using a scanning electron microscope (SEM) and X-ray powder diffractometer (XRD), structural properties of Zn doped BSCCO glass-ceramic samples were determined. Surface morphology of the samples was studied by SEM measurements. Lattice parameters and volume of the samples were calculated from the XRD measurements.
Anahtar Kelimeler
BSCCO,Zn-doped glass-ceramics,thermal properties
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Materials Science-Poland
Dergi ISSN 2083-134X
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2016
Cilt No 34
Sayı 1
Doi Numarası 10.1515/msp-2016-0027
Makale Linki http://www.degruyter.com/view/j/msp.2016.34.issue-1/msp-2016-0027/msp-2016-0027.xml