Enhanced methylene blue removal by ethylenediamine-modified cotton waste activated carbon: Isotherm, kinetic, thermodynamic, and mechanistic insights
Yazarlar (9)
Doç. Dr. Kaan IŞINKARALAR Kastamonu Üniversitesi, Türkiye
Seong Jik Park
Hankyong National University, Güney Kore
Doç. Dr. Aydın TÜRKYILMAZ Kastamonu Üniversitesi, Türkiye
İlker Acar Atatürk Üniversitesi, Türkiye
Fatiha Benmahdi Université De Batna 1, Cezayir
Antonio Cannuli Università Degli Studi Di Messina, İtalya
Huseyin Guran Unal Kastamonu Üniversitesi, Türkiye
Yasaman Sedaghat Semnan University, İran
Ahmad Hosseini-Bandegharaei
Semnan University, İran
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Inorganic Chemistry Communications (Q1)
Dergi ISSN 1387-7003 Dergi Bilgileri (2026)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 09-2026
Kabul Tarihi Yayınlanma Tarihi 01-09-2026
Cilt / Sayı / Sayfa 191 / 0 / – DOI 10.1016/j.inoche.2026.117208
Makale Linki https://doi.org/10.1016/j.inoche.2026.117208
UAK Araştırma Alanları
Fiziksel Kimya
Özet
Cotton waste is an abundant agricultural by-product that can be converted into value-added adsorbents for wastewater treatment. In this study, activated carbon prepared from Gossypium hirsutum L. waste biomass was modified with ethylenediamine (EDA) to improve its ability to remove methylene blue (MB) from aqueous solutions. The adsorbents were characterized by BET, FTIR, SEM, XRD, TGA, CHNS analysis, and pHₚzc measurements. EDA modification increased the specific surface area from 308 to 481 m 2 g −1 and introduced nitrogen-containing functional groups, providing additional adsorption sites. The adsorption performance was evaluated by examining the effects of solution pH, adsorbent dosage, initial dye concentration, contact time, and temperature. Under the optimum conditions (pH 10, 0.1 g adsorbent, 100 mg L −1  MB, 25 °C, and 120 min), the maximum Langmuir adsorption …
Anahtar Kelimeler
Adsorption mechanism | Circular economy | Clean water and sanitation | Nitrogen-doped carbon adsorbent | Responsible consumption and production